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Microscale and Mesoscale Crystallographic Textures of Nanocrystalline Ni-Based Electrodeposits

Identifieur interne : 006920 ( Main/Exploration ); précédent : 006919; suivant : 006921

Microscale and Mesoscale Crystallographic Textures of Nanocrystalline Ni-Based Electrodeposits

Auteurs : P. Cizek [Australie] ; M. R. Barnett [Australie] ; M. D. Nave [Australie] ; E. F. Rauch [France] ; R. Balasubramaniam [Inde]

Source :

RBID : Pascal:11-0310760

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English descriptors

Abstract

The microscale and mesoscale crystallographic textures observed in nanocrystalline Ni, Ni-20 pct Fe, and Ni-50 pct Fe electrodeposits are described. The nanosized grains are arranged in coarse mesoscale colonies. In the as-deposited state, the bulk texture of the Ni-20 pct Fe alloy displays a dominant ?001? fiber parallel to the macroscopic deposition direction (DD). The grains are elongated along the ?001? crystal lattice direction, which is mostly parallel to the local DD, producing a well-defined ?001?//DD fiber microtexture on a local scale. The grain misorientation histograms show some content of low-angle boundaries, frequently associated with the presence of grain clusters, and are dominated by high-angle boundaries with a possible enhanced frequency of Σ5 and Σ7 coincident site lattice boundaries and a significant content of Σ3 twin boundaries. For all three alloys, the coarsened grains, obtained by annealing, within the mesoscale colonies show a fiber mesotexture characterized by a (111) axis approximately perpendicular to the colony hemispherical growth surface (parallel to the local DD). It is surmised that a similar "cobblestone" mesotexture with a (001) fiber axis already exists in the as-received state, as previously proposed by a number of the present authors and as supported by the results on the Ni-20 pct Fe alloy presented here.


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<div type="abstract" xml:lang="en">The microscale and mesoscale crystallographic textures observed in nanocrystalline Ni, Ni-20 pct Fe, and Ni-50 pct Fe electrodeposits are described. The nanosized grains are arranged in coarse mesoscale colonies. In the as-deposited state, the bulk texture of the Ni-20 pct Fe alloy displays a dominant ?001? fiber parallel to the macroscopic deposition direction (DD). The grains are elongated along the ?001? crystal lattice direction, which is mostly parallel to the local DD, producing a well-defined ?001?//DD fiber microtexture on a local scale. The grain misorientation histograms show some content of low-angle boundaries, frequently associated with the presence of grain clusters, and are dominated by high-angle boundaries with a possible enhanced frequency of Σ5 and Σ7 coincident site lattice boundaries and a significant content of Σ3 twin boundaries. For all three alloys, the coarsened grains, obtained by annealing, within the mesoscale colonies show a fiber mesotexture characterized by a (111) axis approximately perpendicular to the colony hemispherical growth surface (parallel to the local DD). It is surmised that a similar "cobblestone" mesotexture with a (001) fiber axis already exists in the as-received state, as previously proposed by a number of the present authors and as supported by the results on the Ni-20 pct Fe alloy presented here.</div>
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